DYEING ACID GN-A (SDS)

DYEING ACID GN-A Date of issue: 3 / 7 / 2 0 1 4 Revision date: 12/01/2019 1 / 5 SAFETY DATA SHEET 1. Identification of the substance/preparation and of the company Trade name : DYEING ACID GN-A Company : PT. INKALI (INDONESIA NIKKA CHEMICALS) Street : Karawang International Industrial City (KIIC) JI.Maligi Ⅱ Lot E-3, Karawang 41361, INDONESIA Tel. : (021) 8904209, 8904309, 8902469 Contact person : info-inkali@niccachemical.com Recommended use : Buffering agent Reference no. : INK-2070 2. Hazards identification Most important hazards and effects : Causes severe skin burns Causes serious eye damage Causes damage to organs GHS classification Physical hazards : Flammable liquids, Category 4 Corrosive to metals,classification not possible Health hazards : Acute toxicity (oral), Not classified : Acute toxicity (dermal), Not classified : Skin corrosion/irritation, Category 1 : Serious eye damage/eye irritation, Category 1 Reproductive toxicity, Not classified : Specific target organ toxicity — Single exposure, Category 1/ Category 2 : Specific target organ toxicity — Repeated exposure, Category 2 Environmental hazards : Hazardous to the aquatic environment - Acute Hazard, Not classified Hazards not mentioned above are not applicable or there is no data is available. Label element Hazard pictograms Signal word : Danger Hazard statements : Combustible liquid (H227) Causes severe skin burns and eye damage (H314) Causes serious eye damage (H318) Causes damage to organs (Respiratory organs, Vessel, Kidney) (H370) May cause damage to organs (Blood, Respiratory system) (H371) May cause damage to organs (Upper respiratory tract) through prolonged or repeated exposure (H373) Precautionary statements [Prevention] : Keep away from heat/sparks/open flames/hot surfaces – No smoking. (P210) Wear protective gloves/protective clothing/eye protection/face protection. (P280) Do not breathe dust/fume/gas/mist/vapor/spray. (P260) Do not eat, drink or smoke when using this product. (P270) Wash thoroughly after handling. (P264) [Response] : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. (P304+340) DYEING ACID GN-A Date of issue: 3 / 7 / 2 0 1 4 Revision date: 12/01/2019 2 / 5 IF exposed or concerned: Call a POISON CENTER/doctor. (P308+P311) Get medical advice/attention if you feel unwell (P314) IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. (P303+P361+P353) Wash contaminated clothing before reuse. (P363) Remove contact lenses, if present and easy to do. Continue rinsing. (P305+P351+P338) Immediately call a POISON CENTER or doctor/physician. (P310) IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. (P301+P330+P331) [Storage] : Store in a well-ventilated place. Keep container tightly closed (P403+P233) Store locked up. (P405) [Disposal] : Dispose of contents/ container in accordance with local authority requirements. (P501) 3. Composition/information on ingredients Distinction of substance or mixture : Mixture Name Concentration CAS No Acetic acid Approx. 9% 64-19-7 Formic acid Approx. 13% 64-18-6 Phosphonic acid compound Confidential Registered Water Confidential 7732-18-5 4. First aid measures First-aid measures after inhalation : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/physician. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after ingestion : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. First-aid measures after Exposure : IF exposed or concerned, call a POISON CENTER or doctor. Notes to physician : No information available. 5. Fire fighting measures Extinguishing agents - fire fighting instructions : Extinguish with Powder. Foam. Carbon dioxide (CO 2 ). Dry sand. Water spray. Unsuitable extinguishing media : No information available. Fire hazard : No information available. Specific fire fighting : Use protective equipment appropriate for surrounding materials. Personal protection (Emergency response) : Wear suitable protective clothing, gloves and eye or face protection. Wear suitable respiratory equipment. Do not breathe fumes from fires or vapours from decomposition. DYEING ACID GN-A Date of issue: 3 / 7 / 2 0 1 4 Revision date: 12/01/2019 3 / 5 6. Accidental release measures Personal Precautions, Protective Equipment and Emergency Procedures : Wear protective clothing as described in Section 8 of this safety data sheet. Environmental precautions : Do not discharge into drains or rivers. Methods and Equipment for Containment and Cleaning up : Remove with liquid-absorbing materials. （ sand, sawdust, peat, etc. ） Place in suitable container. Neutralize spill with soda ash. Prevention Measures for Secondary Accidents : No information available 7. Handling and storage Handling Technical measures : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Precautions for safe handling : Avoid contact with skin and eyes. Wear protective gloves/ protective clothing/ eye protection/ face protection. Do not breathe dust/fume/gas/mist/vapor/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.. Storage precautionary statements Storage conditions : Store in a cool place. Keep container tightly closed. Store locked up. Material used in packaging/containers : No information available. 8. Exposure controls / Personal protection equipment Exposure limits Acetic acid (64-19-7) ACGIH TWA (ppm) 10 ppm ACGIH STEL (ppm) 15 ppm Formic acid ( 64-18-6) ACGIH TWA (ppm) 5 ppm ACGIH STEL (ppm) 10 ppm Appropriate engineering controls : Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. Respiratory protection : Respirators Hand protection : Protective gloves Eye protection : Wear goggles/face shield. Skin and body protection : Protection suit must be worm. Other protection : Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures : Promptly remove any clothing that becomes contaminated. 9. Physical and chemical properties Appearance : Clear liquid Odour : Characteristic odor pH : Approx. 2 (undiluted) DYEING ACID GN-A Date of issue: 3 / 7 / 2 0 1 4 Revision date: 12/01/2019 4 / 5 Melting / freezing point : No data available Viscosity : No data available Boiling point : Approx. 100 ℃ Flash point : Approx. 70 ℃ Decomposition temperature : No data available Vapour pressure : No data available Relative vapour density at 20 °C : No data available Specific gravity density : Approx. 1.03 (20 ℃ ) Solubility : Soluble in water Log Pow : No data available Explosive limits (g/m³) : No data available 10. Stability and reactivity Chemical stability : Stable under normal temperature conditions. Possibility of hazardous reactions : No information available. Conditions to avoid : High temperature Incompatible materials : Strong bases Hazardous decomposition products : No information available 11. Toxicological information Acute toxicity (oral) : Not classified Calculated value Acute toxicity (dermal) : Not classified Calculated value Skin corrosion/irritation : Causes severe skin burn and eye damage Estimated on the basis of the constituents Serious eye damage/irritation : Causes eye damage Estimated on the basis of the constituents Respiratory or skin sensitisation : No information available Germ cell mutagenicity : No information available Carcinogenicity : No information available Reproductive toxicity : No information available Specific target organ toxicity (single exposure) : May cause damage to organs (Respiratory system, Blood) Acetic acid (NITE classification) May cause damage to organs (Respiratory system, Kidney, Vessel) Formic acid (NITE classification) Specific target organ toxicity (repeated exposure) : May cause damage to organs (Upper respiratory tract) through prolonged or repeated exposure Formic acid (NITE classification) Aspiration hazard : No information available 12. Ecological information Ecotoxicity Fish Toxicity(LC50) : 250 mg/l (Red killifish, 96hrs. OECD TG203) Persistence and degradability Biochemical oxygen demand (BOD) : 0 mg/l (Coulometer method, 0.1% water solution) Chemical oxygen demand (COD) : 22 mg/l (JIS K-0102, 0.1% water solution) Persistence and degradability : No information available Biodegradation : No data (OECD 302B) Bioaccumulative potential : No information available DYEING ACID GN-A Date of issue: 3 / 7 / 2 0 1 4 Revision date: 12/01/2019 5 / 5 Ecology - soil : No information available Ozone : None of the chemical components of this product are listed in the Annex of Montreal Protocol. 13. Disposal considerations Dispose of contents/ container in accordance with local authority requirements. Remove to an authorized waste treatment plant. Empty the packaging completely prior to disposal. 14. Transport information UN number : 8 UN proper shipping name : 1760 Class : Corrosive liquids, n.o.s. （ containing Acetic acid, Formic acid ） Packing group : Ⅲ Marine pollutant : Not applicable 15. Regulatory information We can not check up the regulatory information in regard to the substances in your country or region. Therefore we request this matter would be filled by your responsibility. Follow all regulations in your country. 16. Other information DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. The classification is based on the National Institute of Technology and Evaluation (NITE).