CROAKS N_SDS_GHS

1/4 CROAKS N DATE PREPARED : January 13, 2016 REVISION DATE : May 16, 2016 SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME CROAKS N REFERENCE NUMBER INK - 2025 APPLICATION Neutralizing agent for H 2 O 2 bleaching MANUFACTURER PT. INDONESIA NIKKA CHEMICALS Karawang International Industrial City (KIIC) JI.Maligi Ⅱ Lot E - 3, Karawang 41361, INDONESIA CONTACT PERSON Development and Technology Department E-MAIL ADDRESS info-inkali@inkali.co.id EMERGENCY TELEPHONE (021) 8904209, 8904309, 8902469 2 HAZARDS IDENTIFICATION GHS CLASSIFICATION PHYSICAL HAZARDS Not classified HEALTH HAZARDS ACUTE TOXICITY (Oral) Not classified ACUTE TOXICITY (Dermal) Classification not possible SKIN CORROSION / IRRITATION Category 2 SERIOUS EYE DAMAGE / EYE IRRITATION Category 2A RESPIRATORY SENSITIZATION Classification not possible SKIN SENSITIZATION Classification not possible GERM CELL MUTAGENICITY Classification not possible CARCINOGENICITY Classification not possible REPRODUCTIVE TOXICITY Classification not possible SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE Classification not possible - REPEATED EXPOSURE Classification not possible ASPIRATION HAZARD Not classified ENVIRONMENTAL HAZARDS HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE TOXICITY Not classified - CHRONIC TOXICITY Classification not possible GHS LABEL ELEMENTS PICTOGRAMS SIGNAL WORD Warning HAZARD STATEMENTS H315 Causes skin irritation H319 Causes serious eye irritation PRECAUTIONARY STATEMENTS PREVENTION P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash thoroughly after handling. 2/4 CROAKS N RESPONSE P302+P352 IF ON SKIN: Wash with soap and water. P362+P364 Take off contaminated clothing and wash it before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. STORAGE None None DISPOSAL None None 3 COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE OR MIXTURE Mixture INGREDIENTS < Concentration > <CAS No.> Sulfur containing compound Confidential Confidential Anionic polymer Confidential Confidential Water Confidential 7732 - 18 - 5 4 FIRST - AID MEASURES INHALATION If you feel unwell, seek medical advice. INGESTION If swallowed, seek medical advice immediately and show this container or label. SKIN CONTACT IF ON SKIN: Wash with soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. EYE CONTACT IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 5 FIRE - FIGHTING MEASURES EXTINGUISHING MEDIA Extinguish with Powder. Foam. Carbon dioxide (CO 2 ). Dry sand. Water spray. SPECIAL HAZARD ARISING FROM THE SUBSTANCE/MIXTURE Toxic gases (sulfur oxide etc.) may be generated by decomposition. ADVICE FOR FIRE-FIGHTERS Use protective equipment appropriate for surrounding materials. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Do not discharge onto the ground or into water courses. METHODS AND MATERIAL FOR CONTAINMENT AND CLEAN UP Remove with liquid-absorbing materials (sand, sawdust, peat, etc.) Place in suitable container. 7 HANDLING AND STORAGE HANDLING Avoid contact with skin and eyes. Wear protective gloves/ protective clothing/ eye protection/ face protection. Wash thoroughly after handling. Avoid contact with Oxidant. 3/4 CROAKS N STORAGE Store in a cool place. Keep container tightly closed. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION CONTROL PARAMETERS LIMIT VALUES ACGIH TLV : Not established PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. RESPIRATORY EQUIPMENT No specific recommendations. HAND PROTECTION Use protective gloves. EYE PROTECTION Wear goggles/face shield. SKIN PROTECTION Protection suit must be worm. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES Promptly remove any clothing that becomes contaminated. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Colorless clear liquid ODOR Slightly characteristic odor SOLUBILITY Soluble in water pH (undiluted) Approx. 8 MELTING POINT No data BOILING POINT Approx. 100°C SPECIFIC GRAVITY Approx. 1.25 (20°C) FLASH POINT None AUTOIGNITION TEMPERATURE None 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID No information MATERIALS TO AVOID Oxidant HAZARDOUS DECOMPOSITION PRODUCTS Sulfur oxide gas 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY (Oral) Not classified Calculated data ACUTE TOXICITY (Dermal) No information available SKIN CORROSION / IRRITATION Causes skin irritation Estimated from the data of each ingredients. 4/4 CROAKS N SERIOUS EYE DAMAGE / EYE IRRITATION Causes serious eye irritation Estimated from the data of each ingredients. RESPIRATORY SENSITIZATION No information available SKIN SENSITIZATION No information available GERM CELL MUTAGENICITY No information available CARCINOGENICITY No information available REPRODUCTIVE TOXICITY No information available SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE No information available - REPEATED EXPOSURE No information available ASPIRATION HAZARD Not classified Estimated from the data of each ingredients. 12 ECOLOGICAL INFORMATION ECOTOXICITY Not regarded as dangerous for the environment. LC 50 >2,000 ppm (Red killifish, 96hrs.) OECD TG203 MOBILITY The product is soluble in water. BIODEGRADABILITY No data OTHER ADVERSE EFFECTS BOD 44 ppm Coulometer method (0.1% water solution) COD (Mn) 93 ppm JIS K - 0102 (0.1% water solution) 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS In accordance with local regulation, take to special waste incineration plant. Dispose of contents/ container in accordance with local authority requirements. 14 TRANSPORT INFORMATION GENERAL UN Class UN Number UN proper shipping name Packing Group Not regulated by IMDG / IATA Not regulated by IMDG / IATA Not regulated by IMDG / IATA Not regulated by IMDG / IATA 15 REGULATORY INFORMATION PT. INDONESIA NIKKA CHEMICALS is not able to check up the regulatory information in regard to the substances in your country or region, therefore we request this matter would be filled by your responsibility. Follow all regulations in your country. 16 OTHER INFORMATION DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. The classification is based on the National Institute of Technology and Evaluation ( NITE ) .